Another Face of Entropy
Particles self-organize to make room for randomness
Scientists find entropy to be a powerful agent and possibly a practical tool for creating order in microscopic suspensions and biological cells.
References:
Adams, M. . . . S. Fraden. 1998. Entropically driven microphase transitions in mixtures of colloidal rods and spheres. Nature 393((May 28):349.
Dinsmore, A.D. . . . A.G. Yodh. 1998. Hard spheres in vesicles: Curvature-induced forces and particle-induced curvature. Physical Review Letters 80(Jan. 12):409.
Dinsmore, A.D., A.G. Yodh, and D.J. Pine. 1996. Entropic control of particle motion using passive surface microstructures. Nature 383(Sept. 19):239.
Rein ten Wolde, P., and D. Frenkel. 1997. Enhancement of protein crystal nucleation by critical density fluctuations. Science 277(Sept. 26):1979.
Further Readings:
Asakura, S., and F. Oosawa. 1958. Interaction between particles suspended in solutions of macromolecules. Journal of Polymer Science 183.
Gast, A.P., W.B. Russel, and C.K. Hall. 1986. An experimental and theoretical study of phase transitions in the polystyrene latex and hydroxyethylcellulose system. Journal of Colloid and Interface Science 109(January):161. [should be in further readings]
Minton, A.P. 1997. Influence of excluded volume upon macromolecular structure and associations in crowded media. Current Opinion in Biotechnology 8:65.
Sharma, A., and J.Y. Walz. 1996. Direct measurement of the depletion interaction in a charged colloidal dispersion. Journal of the Chemical Society, Faraday Transactions 92:4997.
Wu, C. 1997. Holey device traps light for lasers, filters. Science News 152(Nov. 15):310.
______. 1997. Gazing into crystals balls. Science News 151(April 12):224.
______. 1996. Light gets the bends in a photonic crystal. Science News 150(Nov. 16):309.
Sources:
Anthony D. Dinsmore
Naval Research Laboratory
4555 Overlook Avenue, S.W.
Washington, DC 20375Dennis E. Discher
University of Pennsylvania
School of Engineering and Applied Science
Departments of Mechanical, Chemical, and Bio-Engineering
Towne Building 112
Philadelphia, PA 19104-6315Seth Fraden
Brandeis University
Complex Fluids Group
Martin Fisher School of Physics
Waltham, MA 02254Daan Frenkel
FOM Institute for Atomic and Molecular Physics
Kruislaan 407
1098 SJ Amsterdam
NetherlandsAlice P. Gast
Stanford University
Department of Chemical Engineering
Stauffer III
381 North-South Mall
Stanford, CA 94305-5025Allen P. Minton
National Institutes of Health
National Institute of Diabetes and Digestive and Kidney Diseases
Laboratory of Biochemical Pharmacology
Section on Physical Biochemistry
Bethesda, MD 20892-0830David Pine
University of California, Santa Barbara
Department of Chemical Engineering
Santa Barbara, CA 93106-5080Pieter Rein ten Wolde
FOM Institute for Atomic and Molecular Physics
Kruislaan 407
1098 SJ Amsterdam
NetherlandsPhilip D. Ross
National Institutes of Health
National Institute of Arthritis, Metabolism, and Digestive Diseases
Laboratory of Molecular Biology
Bethesda, MD 20205Adam J. Simon
Merck Research Laboratory
WP 78-302
West Point, PA 19486John Y. Walz
Yale University
Department of Chemical Engineering
P.O. Box 208286
New Haven, CT 06520-8286Arjun Yodh
University of Pennsylvania
David Rittenhouse Laboratory
209 South 33rd Street
Philadelphia, PA 19104Steven B. Zimmerman
National Institutes of Health
National Institute of Diabetes and Digestive and Kidney Diseases
Laboratory of Molecular Biology
Section on Physical Chemistry
Building 5, Room 330
Bethesda, MD 20892
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