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Found:
Primordial Water By Ron Cowen
On a Sunday
evening 19 months ago, 11-year-old Alvaro Lyles, his younger brother,
and five friends were playing basketball in the Lyles'
backyard when they heard what sounded like three sonic booms. At first,
the youngsters thought another boy on the sidelines, throwing rocks, had
made the noise. Then, in a vacant lot some 30 yards away, they spotted
an object they'd never seen before. The black rock was the size and
shape of a squashed grapefruit. A few minutes later, when one of the
boys placed the 2.2-pound chunk in the hands of Eric's father, Orlando
Lyles, it was still warm. Orlando Lyles
recognized the rock for what it was: a meteorite that had just fallen to
Earth. No one guessed, however, the precious cargo that the rock was
carrying. Last August, a
fragment of the meteorite, dubbed Monahans 1998, returned to the
spotlight, this time garnering headlines worldwide. Researchers reported
that the rock contains water from the birth of the solar system. Locked inside
purple-tinged salt crystals that date from the solar system's formation
4.5 billion years ago, the water is presumed to be of the same vintage
as the sodium chloride vessicles. The amount of fluid is minuscule, but
it's the first time that scientists have detected water—an essential
ingredient for life—of primordial origin. Michael E.
Zolensky and Everett K. Gibson Jr. of NASA's Johnson Space Center in
Houston, along with Robert J. Bodnar of the Virginia Polytechnic
Institute and State University in Blacksburg and their colleagues,
describe their findings in the Aug. 27 Science. "This [water]
is the first real sample of the solar nebula gas, the gas from which all
the planets formed," comments cosmochemist Robert N. Clayton of the
University of Chicago. Monahans 1998
belongs to a class of meteorites known as ordinary chondrites, which
astronomers have believed are fragments of asteroids that contain little
or no water. One explanation
for the water in this meteorite is that its parent asteroid acquired it
after the rock formed. A water-rich, icy projectile, such as a comet,
could have plowed into the newborn asteroid and spilled some of its
water. Alternatively, if the water was incorporated into the asteroid as
it coalesced, planetary scientists may have to revise their thinking
about the lineage of ordinary chondrites, says Clayton. The findings have
a far more intriguing implication. To carry a concentrated salt solution
today, Monahans 1998 must have once been in contact with several times
more water than now remains, the researchers note. Clayton agrees with
the team's assessment. "There had to have been quite a lot of water
passing through [the rock], even though only a tiny fraction of it has
been trapped in the crystals," he says. "I think it
changes our whole perception of how the early solar system formed, what
the conditions might have been like, and what the possibility of life
was like this early," says Bodnar. "One of the big questions
we're asking is, Is the Earth unique in terms of having life? If water
was as common in the solar system [as implied] by these findings, then
that would suggest that there were many environments in the solar system
where the conditions were right for the development of life." Water in
chondrites could explain water on Earth, says Alan P. Boss of the
Carnegie Institution of Washington (D.C.). The origin of terrestrial
water has perplexed scientists for decades. Astronomers have
proposed that comets, the frozen, water-bearing émigrés from the outer
solar system, could have delivered much of Earth's water during the
first few hundred million years of the planet's existence. During this
epoch, known as the late heavy bombardment, comets pelted Earth and the
other inner planets at a far higher rate than they do today. However, the ratio
of deuterium to hydrogen in cometary water is much higher than in water
on our planet. Researchers don't yet know the deuterium ratio of the
water in Monahans 1998. If it is lower than that in comets, the finding
could indicate that meteorites or their parent asteroids are just as
important as comets in ferrying water to Earth. A mix of water from
comets and asteroids could be the recipe required to create today's
oceans. Although
scientists have searched for primordial water in space rocks for
decades, they hadn't come up with a drop. Bodnar and his colleagues note
that if the water typically resides within salt crystals, the fragile
evidence could easily have washed away or evaporated. The researchers
succeeded in finding water this time, they assert, because a member of
their team retrieved the rock in record time. As luck would have
it, Monahans isn't very far from the Houston space center. As soon as
news of the meteorite fall got out, Gibson hopped on a plane to west
Texas and met with the Monahans City Council. A Texas native who grew up
just 70 miles from the town, Gibson gave the council his personal
guarantee that if he could borrow the rock, he'd return it within 60
days. With the town's
blessing, he packed up the meteorite in a plastic bag and within 46
hours of its landing had transported it to the NASA center. Researchers
have never before studied a space rock so soon after its arrival on
Earth, Gibson says. He later returned the meteorite, minus a tiny
sample, to the city. In November 1998,
after researchers at the space center had been studying the sample for
several months, Bodnar happened to attend a conference there. Visiting
his former classmate Zolensky, Bodnar peered at a salt crystal from the
meteorite under the microscope. Along with fluid locked inside the
crystal, he and Zolensky saw a moving bubble of gas. Among the materials
that could be present in the meteorite, only water and carbon dioxide
can exist as both a fluid and a vapor at room temperature. Bodnar suspected
that the material was water because liquid carbon dioxide could only
become trapped under extremely high pressure. It was doubtful that
fragile salt crystals could have survived under that condition. At Virginia Tech,
he confirmed his hunch. Chilling the salt sample, a mere millimeter in
length, Bodnar found that the fluid it contained froze at -21.2°C, the
temperature expected for salt water. After bringing the sample back to
room temperature, he illuminated it with the green light of an argon
laser. The light emitted by the fluid showed the characteristic
fingerprint of water. Bodnar was excited
but also cautious. Without doubt, Monahans 1998 contained water, but
could the fluid have entered the rock after it landed? He and his
colleagues were only too aware of scientists' jumping to the wrong
conclusion. In the early 1980s, researchers reported that they had found
primordial water in a meteorite that they had cut open with a diamond
saw. Moisture from the lubricant they had used in the cutting process,
however, had penetrated microscopic fractures within the rock. Gibson
was a member of the chagrined team that had to retract its finding. In this case,
Gibson and his colleagues had an essential clue that the water in
Monahans 1998 hadn't come from Earth. The fluid resided within salt
crystals that have a purplish hue. Newly formed salt is colorless, but
it darkens when cosmic rays and radiation bombard it. Too little time
had elapsed for the discoloration to have taken place on our planet, so
the salt—and presumably its watery cargo—had to have been
incorporated into the rock well before it landed. "The fact
that the salt was purple was evidence that [the water] was in it when
the rock was in space," says Bodnar. Finally,
radioactive dating revealed that the salt crystals were 4.6 billion
years old. "Our conclusion that the water is that old is based on
our interpretation that the salt is that old," Bodnar notes.
"Some of the water clearly penetrated when the salt crystals
formed." The researchers
are now pursuing two lines of study. They hope to analyze the ratio of
deuterium to hydrogen in the water. Because their sample is so small,
they will have to crush the entire salt grain to squeeze out every last
water drop. The team will practice this technique with equally small
samples of salt water made in the laboratory, before preparing to ship
the meteorite-derived fluid to a colleague in England. That colleague
will measure the isotopes using a mass spectrometer. "We can't
afford not to do it right the first time," says Bodnar. In addition,
Zolensky is scouring science museums and meteorite catalogues for rocks
that landed in dry locales and were retrieved soon after they fell. Such
rocks, he reasons, are more likely to still contain traces of any water
they might have carried when they struck Earth. A telltale clue of
ancient water, if Monahans 1998 is any example, is the purplish hue of
salt crystals, he adds. The team may
already have found another specimen. A meteorite called Zag, named for
the arid Moroccan town in which it fell last year, contains purple salt
crystals. It also contains water, and in his laboratory Bodnar is about
to determine how old it is. "We now think
that [water] is much more common in ordinary chondrite meteorites than
people have recognized," says Bodnar. The salt crystals may be so
tiny in most rocks, he notes, that scientists have overlooked them. "We're
pushing the limits of technology here in terms of the amount of sample
we have to work with. If you looked at the container with the Zag [salt
crystal] in it, you'd think the bottle was empty." As with the water
in Monahans 1998, Bodnar and his colleagues are anxious to measure the
ratio of deuterium to hydrogen isotopes within the Zag sample. Even if
the ratio in the two meteorites is a closer match to terrestrial water
than to water in comets, the finding won't entirely explain where
Earth's water came from, cautions theorist Tobias C. Owen of the
University of Hawaii in Honolulu. Meteorites, he
notes, contain 10 times as much xenon, relative to other noble gasses,
than occurs in Earth's atmosphere. In addition, the relative abundance
of xenon isotopes found in meteorites doesn't jibe with the pattern
found on Earth. If meteorites did deliver most of the water to our
planet, they also would have provided xenon, and our atmosphere would
have to have a very different composition, Owen maintains. Back in the town
of Monahans, the chunk of rock in which Zolensky and his colleagues
found the water is no longer there. Last year, after Gibson returned the
rock, the boys and their families sold it to a private collector for
$23,000. So far, according to the researchers, the collector has not
wanted to part with any of his heavenly treasure. The town, however,
has another piece of the same meteorite, a fragment that happens not to
contain water. Found by a deputy sheriff the day after the boys'
discovery, this chunk had gouged a crater in a city street. The town
proudly placed the fragment in a showcase in the lobby of city hall. Travelers in
western Texas are now taking the business route off Interstate 20,
dropping by just to pay homage to the meteorite that promises to change
the way we view our planet's past. From Science
News, Vol. 156, No. 18, October 30, 1999, p. 284. Copyright © 1999,
Science Service. |