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Snowpack chemistry can deplete ozone

After the long, dark polar winter, the sun returns to shine on the high-latitude snows. Simultaneously, the concentration of ozone at low altitudes begins to drop. In research conducted on the Arctic snowpack last spring, scientists used sunlamps to illuminate some of the chemistry of this phenomenon.

The experiment showed that pollutants trapped in Arctic snow, when energized by sunlight, can escape the snowpack and deplete ozone in the lower atmosphere, says Jan W. Bottenheim, a senior scientist at the Meteorological Service of Canada in Toronto, Ontario.

The artificial light stimulated production of nitrous acid and organic chemicals such as formaldehyde in the upper layers of the snowpack. These chemicals, as well as snowbound chlorine and bromine derived from sea salt, then took part in reactions that consumed ozone within the snow, adds Bottenheim.

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